Storable palladacycles for selective functionalization of alkyne-containing proteins.
نویسندگان
چکیده
We report the facile preparation of palladacycles as storable arylpalladium(II) reagents from acetanilides via cyclopalladation. The palladacycles exhibit good stability in PBS buffer and are capable of functionalizing a metabolically encoded HPG-containing protein, thus providing a new type of biocompatible organometallic reagent for selectively functionalizing the alkyne-encoded proteins.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 49 60 شماره
صفحات -
تاریخ انتشار 2013